Molecular alignment using circularly polarized laser pulses

Abstract

We show that circularly polarized femtosecond laser pulses produce field-free alignment in linear and planar molecules. We study the rotational wavepacket evolution of O2 and benzene created by circularly polarized light. For benzene, we align the molecular plane to the plane of polarization. For O2, we demonstrate that circular polarization yields a net alignment along the laser propagation axis at certain phases of the evolution. Circular polarization gives us the ability to control alignment of linear molecules outside the plane of polarization, providing new capabilities for molecular imaging.