Moisture-enhanced trace chloroalkanes detection in bimetallic metal-organic frameworks 3-dimensional photonic crystal.

Abstract

Chloroalkanes have long been a threat to environmental protection and human health, however, rapid and efficient detection of chloroalkanes remains challenging. Herein, 3-dimensional photonics crystals (3-D PCs) based on bimetallic materials of institute lavoisier frameworks-127 (MIL-127, Fe2M, M=Fe, Ni, Co, Zn) demonstrate the great potential of chloroalkanes sensing. Particularly, at temperature of 25°C and dry conditions, the 3-D PC consisting of MIL-127 (Fe2Co) shows optimal selectivity and high concentration sensitivity of 0.0351±0.00007nmppm-1 to carbon tetra-chloride (CCl4), and the limit of detection (LOD) can reach 2.85±0.01ppm. Meanwhile, MIL-127 (Fe2Co) 3-D PC sensor presents a rapid response of 1s and recovery time of 4.5s for CCl4 vapor, and can maintain excellent sensing performance under heat-treatment of 200°C or in the long-term storage (30 days). Mechanism studies indicated that the excellent sensing property derived from the doping of transition metals. Moreover, the moisture-enhanced adsorption of CCl4 for the MIL-127 (Fe2Co) 3-D PC sensor is also observed. H2O molecule can remarkably enhance the adsorption of MIL-127 (Fe2Co) to CCl4. The MIL-127 (Fe2Co) 3-D PC sensor shows the highest concentration sensitivity of 0.146±0.00082nmppm-1 to CCl4 and the lowest limit of detection (LOD) of 685±4ppb under the pre-adsorption of 75ppm H2O. Our results provide an insight for a trace gas detection using metal-organic frameworks (MOFs) in the optical sensing field.