Moisture diffusion and tensile properties of epoxy-based and polyurethane-based flax-glass hybrid FRP under hygrothermal and weathering environments

Abstract

This research presents tensile modulus and strength of flax-glass hybrid FRP (HFRP) flat coupons with different fibre volume fractions and fabric stacking sequences under constant hygrothermal (50 °C and 95% RH) and cyclic weathering (water spray-ultraviolet radiation) environments for six months. Two types of polymer (i.e., epoxy (EP) and polyurethane (PUR)) were employed in HFRP. Fourier transformed infrared spectroscopy (FTIR) was performed to identify the changes in functional groups of flax fibres and polymer matrix after exposures. The glass transition temperature (Tg) of polymer matrix was measured by differential scanning calorimetry (DSC), which was used to study the influence of environmental exposure on Tg. The 3D diffusion coefficients of EP-based flax FRP and glass FRP laminates were determined based on experimental moisture uptake and Fick's law. A coupled mass diffusion-stress analysis based on finite element (FE) model was conducted to simulate the moisture diffusion and swelling behaviour of HFRP. The results showed that hygrothermal and weathering exposures hardly affected tensile modulus of HFRP regardless of the matrix type. After the environmental exposure, EP-based HFRP experienced lower retention ratio of tensile strength (65.4–88.0%) compared to PUR-based HFRP (80.7–94.1%) because of higher moisture absorption in the EP-based HFRP. The influence of fabric stacking sequence on tensile strength reduction varied with different fibre volume fractions in EP-based HFRP, which was explained by the combined effects of the internal stress and damage propagation at flax-glass interface.