Abstract
In symmetric binary and multicomponent systems where two pure components have identical thermodynamic properties (e.g., in mixtures of D- and L-optical enantiomers), the usual equation for the Gibbs phase rule must be modified. For example, in symmetric binary systems, as many as six phases may coexist at a particular temperature and pressure and tricritical points are possible.
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More From: Journal of the Chemical Society, Faraday Transactions 2
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