Abstract
The aim of this work is to develop a new type of carbon-ceramic membranes for the removal of pharmaceutical substances from water. The membranes were prepared by the chemical modification method using an organosilicon precursor—octadecyltrichlorosilane (ODTS). Graphene oxide, multi-walled carbon nanotubes with carboxylic groups, and single-walled carbon nanotubes were used in the modification process. The filtration properties and adsorption properties of the developed membranes were tested. In order to characterize the membrane, the water permeability, the change of the permeate flux in time, and the adsorbed mass of the substance were determined. Additionally, the surface properties of the membranes were characterized by contact angle measurements and porosimetry. The antibiotic tetracycline was used in the adsorption tests. Based on the results, the improved adsorption properties of the modified membrane in relation to the unmodified membrane were noticed. Novel ceramic membranes modified with MWCNT are characterized by 45.4% removal of tetracycline and permeate flux of 520 L·h·m−2·bar−1. We demonstrated the ability of modified membranes to adsorb pharmaceuticals from water streams that are in contact with the membrane. Novel membranes retain their filtration properties. Therefore, such membranes can be used in an integrated filtration–adsorption process.
Highlights
IntroductionCare Products (PPCPs) that pollute the aquatic environment [1,2]
Published: 28 June 2021For about 20 years, there has been a growing interest in Pharmaceutical and PersonalCare Products (PPCPs) that pollute the aquatic environment [1,2]
Ceramic-based membranes modified by carbon compounds demonstrate the ability to adsorb pharmaceuticals from water streams that are in contact with the membrane
Summary
Care Products (PPCPs) that pollute the aquatic environment [1,2] These pollutants come, to a large extent, from pharmaceutical plants and hospitals and from agriculture (animal husbandry and plant cultivation) and households due to the widespread use of antibiotics and non-prescription drugs [3]. This accessibility and use of pharmaceuticals make these compounds appear in increasing concentrations in water and soil. The concentrations of these substances are relatively low (μg/L) [4], which makes it difficult to measure them.
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