Abstract
Models common to those for phase transitions correlating diffusion with thermodynamics are advanced to describe the growth of oxides and sulfides on several transition metals and alloys in single oxidant gases at temperatures ranging from 400° to 1400° C. Ambipolar lattice and short-circuit diffusion describe reactant transport and growth of superficial scales; these diffusion properties are combined with theory for general and cellular precipitation to explain development of internal oxidation zones beneath scales on alloys.
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