Modelling of overall plastic deformation in rubber-toughened polymers

Abstract

In this paper, we provide a constitutive model for overall (macroscopic) plastic deformation behavior in a rubber-toughened polymer blend. A porous plasticity theory is employed as a basis for the constitutive modeling. In our investigation, the polycarbonate (PC) is chosen as a matrix material of polymer blend. First, the true uniaxial stress-strain relation for PC, which is an important part of the constitutive model, is carefully measured. Secondly, finite element analyses of neck propagation in a tensile specimen of PC are performed to test the efficiency of the introduction of the accurately measured true stress-strain relation into the model. Then, in order to investigate local and average deformation behavior of the matrix material (PC) around cavitated rubber particles in polymer blend, an axisymmetric unit cell analysis is carried out. Finally, finite element analyses of the neck propagation in a tensile specimen of a rubber-toughened PC are performed, and the numerical results are compared to experimental results. It is revealed that the present constitutive model has the ability to well reproduce the behavior of a rubber-toughened polymer blend with rather small volume fraction of rubber particles, which is up to about 10%. However, for blends with larger volume fraction of the rubber particles, the discrepancy between the computational and the experimental results increases. Several possibilities of enhancing the model are discussed.