Abstract

So far, the torrefaction process has been merely discussed based on the physical and chemical characteristics of the final product, but the mechanism has not been yet pondered and investigated. Thus far, microwave torrefaction has been predominately used for thermal pre-treatment; therefore, a paradigm shift in the methodology has been introduced by using a Joule heating system. The article mainly focuses on the thermal engineering aspect of the torrefaction process. The densified black pine underwent thermal pre-treatment at a temperature of 523 K. The furnace used for torrefaction was initially improvised to carry out thermal degradation at quasi-static/dynamic conditions. A 3D PDE thermal model was developed to determine the numerical solution and temperature distribution across a black pine pellet. To compare the effect of the linear ramping profile, time-dependent as well as fixed Dirichlet conditions were applied to the proposed model. The mass distribution, duration of the torrefaction process, the effect of Nusselt and Reynold’s number of inert gas, and thermal history are some of the factors whose influence on the numerical solution was investigated. The simulation of thermal pre-treatment and its effect on the heat transfer characteristic was examined with help of a PDE thermal model, whereas the numerical solution of diffusion of the product of reactions was determined by solving the partial differential equations with the help of the discretisation method (PDEPE). The densification of black pine was performed in a ring die, whereas initial milling of biomass was carried out using a 1.5 mm sieve size. The system was found to have a homogeneous distribution in energy and temperature with time, whereas the amplitude of heat flux along the radial direction was reduced by 15% if the same pellet underwent torrefaction for a duration of 5 min in dynamic mode. Similarly, a 64.46% drop in amplitude of heat flux along the azimuth plane could be seen while performing torrefaction in a time-dependent thermal history. However, the relative amplitude of the heat flux at the centre of the pellet was estimated to be lowered by 98.41% along the vertical axis for heating a pellet in a quasi-static condition. The net change in the mass fraction of carbon dioxide across the boundary film was seen to be 40% higher than that of carbon monoxide. The rate of change of mass fraction of carbon monoxide across the boundary film was increased by 7–11% with the increase in torrefaction time. A 6.8% rise in the evaporation of water was noticed during the first half interval of torrefaction (from 5 min to 10 min). In the second half, from 10 min to 15 min, it was merely increased by 5.8%. A relative drop of 17.24% in water evaporation was estimated in the dynamic state of the system.

Highlights

  • In the coming years, the energy demand will surge dramatically, and it will become very important to focus on the productivity of biofuel

  • The numerical solution for applying the different thermal conditions in the torrefaction process was analytically examined with the help of the PDE thermal model for a biofuel pellet

  • The effect of nitrogen gas on the temperature profile of the material was determined and it was found that an increase in the average Nu number beyond 10 would influence thermal homogeneity along the tangential plane in the quasi-static torrefaction, whereas it merely reduced the temperature scale when a pellet of the same size was subjected to dynamic torrefaction

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Summary

Introduction

The energy demand will surge dramatically, and it will become very important to focus on the productivity of biofuel. Another aim of energy production will be to reduce the bulk of the material and increase the quality of energy production so that the capital investment and labour costs can be minimised. Torrefaction is a thermal pre-treatment process that is performed at 200–300 ◦C to impart a remarkable change in the biomass characteristics (handling, milling and co-firing). Far, this methodology has been confined to pilot scales and many technical and economic hurdles have not yet been addressed, which hinders its introduction into commercial usage

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