Abstract

Thermally reactive materials have caused many serious accidents involving storage and transportation, due to being thermally reactive. The safe storage and management of these materials still is a critical problem in many countries. We studied the thermal hazard of thermal reactive materials, such as a propellant, by employing differential scanning calorimetry (DSC) non-isothermal tests and isothermal tests, and then comparing the kinetic parameters by isothermal and non-isothermal of kinetics, avoiding the mistaken results of the single thermal analysis model. The chosen approach was to obtain reliable kinetics of thermal decomposition by safety and effective technology by modelling method, which acquired the safety parameters of storage condition that could be applied as thermal reactive materials safer design during storage safety conditions and relevant operations.

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