Abstract

We study the dynamics of an ultra-thin reactive liquid film flowing down a heated vertical fiber under the influence of gravity. A key focus is on the impact of the van der Waals attraction, which is proportional to h−3, where h denotes the film thickness. Linear stability analysis of the film flow reveals that the van der Waals attractions and the Marangoni effect enhance the instability. Furthermore, instability is reduced by exothermic chemical reactions, while it is strengthened in the case of endothermic chemical reactions. Moreover, the weakly nonlinear stability of the film flow is studied. The results indicate the possibility of both subcritical and supercritical stability in the system. Lastly, direct numerical simulations of the evolution equation are conducted for various flow parameters. These results enhance our understanding of the intricate interplay of chemical reactions, thermal effects, and intermolecular forces influencing the liquid film dynamics in complex systems.

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