Abstract
Ozonation of benzaldehyde in its aqueous solutions based on mechanistic approach and incorporating ozone decomposition model is presented in this work. As the basis the modified and extended HSB model of ozone decomposition with phosphates and carbonates reactions included has been applied. It was then tuned with the literature data and the results of our own measurements on ozone decay in aqueous solutions. The model was extended to model benzaldehyde oxidation reactions in the aqueous solutions. Model predictions compare favorably against experimental data obtained in the range of pH 2.3 to 8 with or without radical scavenger (t-butanol).
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