Abstract
The nonlinear transient extensional and steady-state shear rheological properties of dilute polystyrene solutions of molecular weight 3.9 and 10.2 million in a theta solvent are predicted using Brownian dynamics (BD) simulations with the bead-spring model. Full hydrodynamic interaction is incorporated into BD simulations using the Rotne–Prager tensor. The hydrodynamic interaction parameter h* is obtained a priori by matching the drag force from a fully extended bead-spring model in extensional flow with that from Batchelor’s theory for a cylindrical rod [Hsieh et al. (2003)]. The agreement between experimental data [Gupta et al. (2000)] and simulation results for the transient Trouton ratio versus strain is good from low to medium strains. However, the plateaus at high strains predicted by the simulations are higher than measured. We also find that hydrodynamic interaction hinders the unraveling of a polymer chain in strong extensional flow (Wi≫1) due to the hydrodynamic clustering of beads. In steady she...
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