Modeling and experiments of the thermal degradation behavior of PMMA during laser transmission welding process

Abstract

Reducing thermal degradation of plastics during laser transmission welding (LTW) process is the key to obtain high-quality weld seam. In this study, a thermal degradation prediction model is proposed. First, using polymethyl methacrylate (PMMA) as an exemplary material, the weld seams are prepared at different process parameters, including the laser power, welding velocity and carbon black (CB) content. Full characterization of the prepared weld seams was performed through shear tests, scanning electronic images, and ultra-depth-of-field microscope. The results reveal that thermal degradation occurs with bubbles at the interface and decreases the shear strength of the weld seam. Second, the thermal history model during LTW is simulated through a 3-D transient heat transfer finite element method (FEM), where the highest temperature is extracted to aid in comprehension of thermal degradation mechanism. Third, a thermal degradation prediction model is proposed based on the thermal history model and thermal degradation kinetic model which is solved by the thermogravimetric analysis (TGA). The results from the proposed prediction model is consistent with the occurrence of the initial thermal degradation and the trend of shear strength of the weld seam. Therefore, this study might present a potential way to optimize the processing window by effectively suppressing the appearance of thermal degradation.