Abstract
AbstractThe continuous and lattice dynamic models of the macromolecules in the LC state are considered. The relaxation properties of polymer chain in the nematic LC state may depend on both the variation of the conformation in the ordered state and on the activation barrier of the molecular field. The calculation and comparison of the longitudinal and transversal relaxation spectra for the continuous and discrete rotameric mechanism of the mobility are performed. For the simplest model of the heterogeneous polymer chain for continuous dynamic models the complicated relaxational behavior with two longitudinal and two transversal branches is manifested. The dynamic properties of the lattice dynamic model with spacer consisting of several bonds are considered.
Published Version
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