Dynamic light scattering by permanent gels: Partial heterodyne and nonergodic medium methods for data evaluation

Abstract

AbstractFour relationships between the intensity and field correlation functions have been used in the analysis of the measured intensity correlation function in dynamic light scattering for four different polymer gel samples. The evaluation of diffusion coefficients was performed using inverse Laplace transformation (ILT) and the cumulante method, respectively. The diffusion coefficients derived from the nonergodic medium method are almost the same as those from the partial heterodyne method when ILT is used. ILT can give similar results by all four procedures even when large baselines for the nonergodic medium method exist. The cumulants method leads to incorrect diffusion coefficients from the correlation functions derived using the nonergodic medium method.