Abstract

Epitaxial BaF 2 grown by vacuum deposition has been investigated as: (a) an insulating layer in MIS capacitors on narrow-gap semiconducting PbSe (111)-surfaces; and (b)a buffer layer for growth of epitaxial PbSe onto (111)-Si substrates. The MIS capacitors revealed breakdown strengths up to 4 MV cm −1 at 77 K and capacitance-voltage curves followed theoretical predictions from accumulation to inversion. Estimated interface state densities were ∼10 12 cm −2 V −1 and carrier lifetimes were in the picosecond range. In preliminary experiments, Schottky diodes were fabricated on the top PbSe layer of PbSe/BaF 2/Si stacks. These diodes revealed resistance-area products up to 0.14Ωcm 2 at quantum efficiencies of ≃ 40%, corresponding to detectivities of up to D∗ (λ) p ≃ 1.5 · 10 10cmHz 1 2 W −1 at the peak wavelengths λ p ≃ 7 μm at77 K.

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