Mineralogy and geochemistry of the Morro do Engenho lateritic nickel deposit, Goiás Alkaline Province, Brazil

Abstract

The Morro do Engenho lateritic nickel deposit results from the action of weathering processes on the alkaline mafic-ultramafic rocks that make up the Cretaceous zoned intrusive body belonging to the Goiás Alkaline Province. Historically, the deposit is classified as a silicate one, and mineralization is present especially in phyllosilicates such as serpentine and chlorite. By identifying Ni-bearing phases and providing the lithogeochemical characterization of weathering profiles, this study aims to provide further insights into the metallogenetic processes and controls acting on the mineralization of the Morro do Engenho lateritic Ni deposit. The following methods were used: petrographic studies, SEM-EDS, XRD and lithogeochemical characterization of the weathering profiles developed on each of the parent rocks that make up the body. The Morro do Engenho intrusive massif is formed by a dunite core, surrounded by a peridotite/pyroxenite zone, an alkaline gabbro zone and more externally by a syenite-nepheline zone. The lateritic profile constitutes eight weathering horizons, stacked one upon another from the bedrock namely: (i) saprock, (ii) lower saprolite, (iii) ferruginous saprolite, (iv) ocher saprolite, (v) plasma zone, (vi) lateritic duriccrust, (vii) silcrete and (viii) topsoil. Most Ni mineralization occurs in the lower saprolite, ferruginous saprolite and ocher saprolite zones. The findings pointed to the presence of Ni in silicate mineral phases, represented by serpentine, chlorite, smectite, as well as in Fe and Mn oxyhydroxides. The depressed area, located between the two major topographic elevations, has the highest Ni enrichments, which according to mass balance calculations can account for up to 40%. Hydrodynamic factors, by dissolution/precipitation of silicates in saprolite horizons of dunite core, are suggested as possible agents in the remobilization of Ni, among other mobile elements, to topographically flat zones. The geometry of the Morro do Engenho deposit show that lateral redistribution by hydrodynamic factors could also account for the mineralization of areas peripheral to the dunite core, composed of pyroxenite and gabbro-derived lateritic profiles. The direction of regional groundwater flow, strongly influenced by topography, would also be an important factor in the remobilization of Ni, as well as the mechanical transport of lateritic materials. Silicate mineralization predominates in the Morro do Engenho deposit, concentrated in Mg hydrosilicates and clay minerals; oxide mineralization also occurs, mostly in Fe and Mn oxyhydroxides. The findings discussed in this paper can broaden the understanding of metallogenetic processes involved in the genesis of lateritic nickel deposits. .