Middle Devonian volcanic rocks in the Weibao Cu–Pb–Zn deposit, East Kunlun Mountains, NW China: Zircon chronology and tectonic implications

Abstract

The Weibao copper–lead–zinc deposit, located in the eastern part of the Qimantagh area, East Kunlun Orogenic Belt (EKOB), consists of three skarn ore blocks known as Weixi, Main and Weidong from west to east. The mineralization within the Weibao Cu–Pb–Zn deposit is hosted by the Mesoproterozoic Langyashan Formation. In this study, we describe for the first time basaltic lavas that intruded into this host sequence and chronological, isotopic, major and trace element data of these volcanic rocks are presented here to constrain their eruption age as well as the tectonic setting. Two basaltic lava samples yield sensitive, high-resolution ion-microprobe (SHRIMP) U–Pb zircon ages of 393.0±5.5Ma–392.0±5.0Ma, indicating that volcanic rocks in the Weibao deposit erupted in Middle Devonian. The majority of the volcanic rocks have compositions characterized by high potassium, light rare earth element (LREE)-enriched patterns in chondrite-normalized rare earth elements (REE) diagrams, and evident enrichment of Rb, Ba and K and depletion of Th, U, Nb and Ta contents in primitive mantle-normalized patterns, although the degrees of enrichment and depletion are variable. These characteristics of major and trace element data highlight a hornblende-dominated fractionation during ascent of magmas. The εHf(T) values of zircons are relatively scattered and slightly enriched, ranging from −2.6 to +7.5. Modelling the features of the major, trace and isotopic element data indicates a hybrid origin involving combined depleted mantle (and hence asthenospheric mantle) and melts and/or fluids inherited from an early subduction event. Besides, these geochronological and geochemical data, together with previously published data in the EKOB, suggest that the Weibao basaltic lavas formed in a post-collisional setting, and that the Qimantagh area underwent strong interactions between mantle and crust in Early Paleozoic–Middle Devonian.