Microwave-assisted rapid degradation of Methyl red dye using Polyfuran/Polythiophene and its Co-oligomers as catalysts

Abstract

The work reports for the first time microwave-assisted degradation of Methyl Red (MR) dye using polythiophene (PTh), polyfuran (PFu) and its co-oligomers. The co-oligomers were synthesized by sonication using varying mol ratios of PFu/PTh (80:20, 50:50 and 20:80). The polymers and its co-oligomers were analyzed for their spectral and morphological properties using FTIR, UV–visible and scanning electron microscopy (SEM) coupled with elemental mapping. The oligomers as well as pristine polymers were used as microwave active catalysts to degraded Methyl Red (MR) dye. The degradation was found to follow the pseudo-first-order model. Maximum degradation of 99% was achieved using PFu/PTh-50/50 as catalyst. Scavenging tests were also carried out to confirm the generation of radicals responsible for the effective degradation of the dye. The LCMS studies were used to explore the degraded fragments and a plausible mechanism was proposed to reveal the degradation pathway.