Abstract

Iron-substituted SBA-16 materials have been synthesized by using direct microwave synthesis method under weak acidic conditions. Different iron species including isolated framework iron species, iron cluster and iron oxides were formed by adjusting the pH value and Si/Fe molar ratios. All the materials has been characterized by XRD, N 2 sorption and SEM. Lewis acid catalyzed Friedel-Crafts type alkylation reaction of benzene with benzylchloride has been investigated over Fe catalysts prepared with different pH values and iron contents.

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