Abstract
Microwave heating of high-loading TEMPO-methyl resin with functionalized styrenyl monomers in an ADVANCER™ preparative scale microwave synthesizer affords larger resin beads (>375 μm) via living free radical polymerization (LFRP). Unlike homogeneous MAOS reactions, the heterogeneous LFRP reaction is not directly scalable and required significant optimization. Under modified conditions, high-loading Rasta resins (>3.8 mmol/g) are reproducibly obtained in 40–100 g quantities.
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