Microwave-assisted Synthesis, Characterization, Photocatalytic Degradation of Antibiotics, and Fluorometric Selective Sensing Activity of g-C3N4 Supported CuO Composites.

Abstract

Herein, we have designed for the fabrication of a series of g-C3N4/CuO composite by using one-step microwave-assisted synthesis for the degradation of antibiotics and detection of nano-molar range of toxic heavy metal ions. The synthesized g-C3N4/CuO composites were analyzed and characterized to know the structure, phase, surface area, absorption region, bandgap, and size of the composites. From the observation of TEM and XRD measurements, g-C3N4/CuO composites have hexagonal shape with average diameter of the particles is 25 ± 5nm. The observed band gap values from UV-vis DRS for g-C3N4 nanosheets and CuO NPs are 2.64eV and 1.72eV. The synthesized g-C3N4/CuO composite has prodigious specific surface area (32.47 m2/g), which is the evident for superior heterogeneous catalytic applications. Therefore, the synthesized g-C3N4/CuO composites were tested for the degradation of antibiotics such as tetracycline (TC) and ciprofloxacin (CIP) under UV light illumination, it shows 88.02% and 90.01% degradation was observed within 1h due to the matching optical band gap and internal charge transfer of excitons with in the heterojunction surface among g-C3N4 and CuO in the composite than the individual components (g-C3N4 and CuO) due to the high surface area and tiny particles of CuO were randomly deposited on the surface of g-C3N4 nanosheets. The catalytic reduction reaction follows as pseudo-first order equation and reused for 5 consecutive cycles without remarkable loss of catalytic activity. Moreover, the synthesized CuO NPs and g-C3N4/CuO composites were used as a prominent fluorescence sensing probe for the selective detection of Pb2+ in nano-molar range of concentration with Ksv is 1.38 × 104mol- 1dm3. It was observed as a linear relationship based on the change in intensity, the limit of detection was determined to be 0.184 nM.