Microstructure evolution and properties of red mud/slag-based cenosphere/geopolymer foam exposed to high temperatures

Abstract

In this study, a type of red mud/slag-based cenospheres/geopolymer foam was directly fabricated using the direct foaming method at room temperature. The effects of high-temperature exposure (700–1100 °C) on the phase evolution, pore structure, and properties of the foams were investigated. The results showed that the untreated foam was amorphous structure. The porosity of the foams increased from 36.4 ± 0.6% (1 wt%) to 71.9 ± 0.1% (5 wt%) with the addition of H2O2. The compressive strength of the foams was 1.20–18.15 MPa, which was attributed to the good bond between the cenospheres and red mud/slag-based geopolymer matrix, the fractured spheres, and the crack deflection. After this high-temperature exposure, the foam crystallized mainly into the leucite and mullite phases. The density and compressive strength of the foams decreased as the exposure temperature increased. The thermal conductivity of the foams reached the lowest value of 0.169 W/(m⋅K) and 0.108 W/(m⋅K) with 5 wt% H2O2 before and after the exposure, respectively. These foams have demonstrated good potential for application in the building insulation field.