Microstructure design of polypropylene/expandable graphite flame retardant composites toughened by the polyolefin elastomer for enhancing its mechanical properties.

Abstract

The enhanced toughness of flame-retardant polymer composites is still a big challenge due to the deterioration of their mechanical properties. In this work, polypropylene (PP)/nanohybrid expandable graphite (nEG) flame-retardant composites toughened by octene–ethylene copolymer (POE) were fabricated for obtaining good mechanical properties and flame retardancy. The structure, rheological and crystallization behaviors, morphology, flame retardancy, and mechanical property of PP/nEG/POE composites with different contents of POE were investigated. Results show that the elongation at break and impact strength of PP composites were significantly improved due to the incorporation of POE. The elongation at break and notched impact strength of toughened PP composites with only 20% POE were increased to 521.6% and 22.9 kJ m−2 from 16.1% and 9.3 kJ m−2 for untoughened PP composites, respectively. The scanning electron micrography (SEM) images showed that POE droplets were dispersed finely and uniformly in the PP matrix, exhibiting a typical two-phase structure. Additionally, the interfacial adhesion between the matrix and inorganic particles was enhanced due to the addition of POE. The rheological behaviors of PP composites showed improved elasticity and longer relaxation times, and a stress-yield behavior appeared with the addition of POE. The interfacial interaction in PP composites was enhanced and the formation of an interparticle network was further proved. Additionally, the toughened PP/nEG20 composites with different contents of POE exhibited excellent flame retardancy. Therefore, the toughened flame-retardant PP composites should possess a wider range of application potential.