Abstract
Ca-doped (1; 1.7; 5 and 10mol% CaO) cobalt oxide single crystal samples, having an [100] orientation, were annealed at 1100°C in air or argon atmosphere. The microstructure was examined by means of transmission electron microscopy (TEM). The electron energy loss spectroscopy (EELS) analysis of the matrix and precipitates has been performed in order to understand the conductivity behavior of these materials. An extensive precipitation of Ca-free Co3O4 spinel crystals was observed with increasing Ca content and oxygen activity. It is suggested that the electrical conductivity changes in this material may be related to this precipitation, because it changes the electronic state of cobalt cations.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
