Microstructural Evolution in 9%Cr Heat Resistant Steels under Creep Conditions

Abstract

Microstructural design of a new generation of 9%Cr steels for fossil power plants is considered. It was shown that microstructural stability of 9%Cr steels impairs their creep resistance. Two types of restoration processes can occur in the heat resistance steels under creep conditions: (i) normal grain growth and (ii) dynamic recovery. The first process associates with the migration of high-angle boundaries (HAGB) of blocks of tempered martensite lath structure (TMLS). However, their migration is negligible even during creep deformation. Boundaries of packets and prior austenite boundaries (PAB) are effectively pinned by precipitations of M23C6and Laves phase Fe2(W,N). The second process consists of transformation of lath boundaries to subboundaries and their subsequent migration (subgrain coarsening) under creep. Under aging the migration of low-angle boundaries (LAGB) is retarded by uniformly distributed nanoscale M(C,N) dispersoids and particles of M23C6precipitated on these boundaries under tempering. Under creep the dissolution of M23C6carbides located along LAGBs and coagulation of uniformly distributed M(C,N) carbonitrides facilitates LAGB migration. It was shown that the normal grain growth is not important for deterioration of creep strength. Conversion of the lath boundaries into subgrain boundaries strongly decreases creep rate. In contrast, continuous subgrain coarsening is the main process restricting the ability of the 9%Cr steel for long-range service under creep conditions. Tertiary creep is attained due to the occurrence of subgrain coarsening.