Microstructural and mechanical properties of a high-strength geopolymer based on coal-based synthetic natural gas slag cured at ambient temperature

Abstract

In this study, an effort was made to enhance the mechanical properties of coal-based synthetic natural gas slag (CSNGS) geopolymer with curing at ambient temperature by incorporating ground granulated blast furnace slag (GBFS). The effects of GBFS content, activator modulus and alkali content on the compressive strength of CSNGS-GBFS (CG) geopolymers were analyzed, and the microstructural characteristics and the compositional evolution of reaction products were also investigated by X-ray diffraction (XRD), scanning electron microscope-energy dispersive spectrometer (SEM/EDS), Fourier transform infrared spectroscopy (FT-IR), and thermogravimetric analyzer (TG) tests. It was found that the mechanical properties of CG geopolymers was highly dependent on the of GBFS content. When the GBFS content was 50%, the 1-day and 28-day strengths of the geopolymer were 50.8 MPa and 120.2 MPa, respectively. Increasing alkali content resulted in the strength of geopolymer to increase and then decrease, whereas, the strength of geopolymer increased monotonically with a decrease in activator modulus. The results also showed that with increasing the GBFS contents, the characteristic peaks corresponding to the gels in the XRD patterns became gradually obvious with highly denser microstructures formed by a number of gels in the SEM micrographs, and the Ca/Si ratio and Ca/(Si + Al) ratio of the reaction products were increased, revealing that the gels generated in CG geopolymers was a mixture of N-A-S-H and C-(A)-S-H gels, which corroborated with the observed the stretching vibration of Si–O-T (T = Si or Al) in FT-IR spectrum shifted from 1013 cm−1 to 990 cm−1 and the corresponding temperatures of the mass loss peaks increased form 104 °C–114 °C. In addition, the dissolution of raw materials was promoted owing to the reduction of the activator modulus, but the change of activator modulus had little effect on the thermal stability of the gels. These findings suggest that CSNGS has the potential to prepare high-strength geopolymers at ambient temperature, providing an attractive avenue for reducing the environmental impact of CSNGS and conserving natural resources.