Microstructural and chemical transformations accompanying deformation of granite in a shear zone at Mi�ville, Switzerland; with implications for stress corrosion cracking and superplastic flow

Abstract

At Mieville, in the Aiguilles-Rouges Massif, granitic rocks of the basement are deformed into mylonites within a major subvertical shear zone. The ambient temperature during translation is estimated at 250° C±30° C from fluid inclusion filling temperatures in syntectonic microveins, from Δ 18O quartzilmenite of+15%, and from mineralogical criteria. Porphyroclasts of both oligoclase and orthoclase feldspar decrease from initial diameters of 20 mm and assume elliptical shapes during progressive deformation, due to recrystallisation of the margins to ultra-fine polygonal grains which extend out from the porphyroclasts in thin trails: the final stable grain size is <5 μ. The recrystallised feldspar has a composition of the parent porphyroclast,+albite, requiring relative gains of Na and losses of K+Ca compared to the precursor, and implying short range redistribution of the components during deformation. Decrease of free energy associated with the deformation catalysed change in feldspar composition, coupled with stored strain energy in the porphyroclasts may account for recrystallisation to a stable aggregate of ultrafine grain size. The long trails imply exceptionally high ductility, which, coupled with microstructural criteria, and admixture of quartz from neighbouring pure quartz aggregates by grain boundary sliding, is interpreted in terms of superplastic flow. Estimated temperatures of T/T m≈0.2 for the inferred superplastic deformation is lower by a factor of 2 than previously recorded for this flow michanism in silicates. The feldspar and quartz probably accomodated grain boundary sliding by intercrystalline diffusion. Biotite responds to deformation by bendgliding, kinking, and recrystallisation in mantles. The reaction of high-Ti parent grains to low-Ti biotite+Fe-muscovite+ ilmenite+chlorite is catalysed at all of these microstructural sites. Progressive deformation of the fine-grained products in the mantles is coupled with steady reaction to low-Fe muscovite+epidote+ sphene+rutile resulting in exceptionally ductile trails, as for the case of feldspar. Biotite grains have pervasive networks of nondisplacive intragranular fractures. At the fracture tips increase of the stress intensity has catalysed the reaction of high-Ti parent grains to low-Ti biotite+muscovite+ ilmenite which occupy the fractures. The fractures propagate and coalesce resulting in mechanical breakdown of the parent grains: these microstructures are believed to be examples of natural stress corrosion cracking. These features are also abundant in feldspar porphyroclasts where at fracture tips orthoclase→secondary orthoclase+albite, and oligoclase→secondary oligoclase+albite. Stress corrosion cracking may be significant in the steady state deformation of crustal rocks at low temperatures when intracrystalline plasticity is not generally dominant. Two way mass balance calculations utilising major and selected trace element data, reveal that deformation of the granite was essentially isochemical, involving average additions of <1 % H2O+CO2, at approximately constant specific gravity. The parameters Fe2+/∑Fe and δ18Owhole rock maintain relatively constant values across the shear zone, and this also implies limited participation of fluids in the deformation. Alkali elements and titanium display the largest percentage variation during progressive deformation, whereas SiO2, Al2O3, and P2O5, together with V, Ni, Cr,Y,Zr, and Nb remain relatively constant. All variations decrease at increasing states of deformation and this is interpreted in terms of mechanical mixing of chemical inhomogeneities of the granite precursor within the shear zone. Constraints imposed by variations in abundance of the relatively immobile elements imply that volume changes accompanying deformation in the shear zone were less than ±10%.