Microscopic Evidence for the Correlation of Micellar Structures and Counterion Binding Constant for Flexible Nanoparticle Catalyzed Piperidinolysis of PS− in Colloidal System

Abstract

Abstract The interest to determine the ionization degree of counterion initiates the need to study the relationship between counterion binding constant (RX Br) and the growth of self-assembly micellar structure. This paper discussed the microscopic evidence for the correlation of counterion binding constant values and micellar structure of cationic surfactants in the presence of phenolates and 2-ethyl phenolates ions in flexible nanoparticle (FN)-system of ionized phenyl salicylate-catalyzed piperidinolysis. The sizes of micelles were determined by particle size analysis. Transmission electron microscopy (TEM) results showed a spherical micellar structure for phenolates and 2-ethyl phenolates ions at counterion binding constant values 6.3 ± 1.0 and 24.0 ± 1.1 respectively. A study using a semi-emperical kinetic technique in published article proved that the suggested micellar structures at respective counterion binding constant values corresponded with the present microscopic evidence.