Abstract
Heats of ion exchange and adsorption of water vapors on cation-substituted clinoptilolites are studied by microcalorimetry. Based on the results obtained, the composition of hydrates of Na+, Cs+, Co2+, and Ba2+ ions on various ion-exchange sites of clinoptilolite is determined. Their structure is identified using the combined analysis of calorimetric and X-ray diffraction data. The usefulness of energy–stoichiometry approach to the discussion of the results of adsorption calorimetry study of the interaction between water and cation-substituted clinoptilolites is demonstrated.
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