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https://doi.org/10.1016/j.arabjc.2011.03.021
Copy DOIJournal: Arabian Journal of Chemistry | Publication Date: Apr 2, 2011 |
Citations: 20 | License type: cc-by-nc-nd |
Adsorption/desorption of water vapour on raw Saudi bentonite (RB) is proposed as a heat energy storage. This is most readily achieved by adsorption and desorption of water vapour on RB at different temperatures as a function of time. The RB subjected to preheating temperature of 200°C, before subjecting to the adsorption process carried out. The IR spectra of RB before adsorption of water vapour at 298 and 313K were studied. The adsorbed and desorbed water vapour from bentonite surfaces at 298 and 313K was determined at different time. The adsorptive capacities of RB sample at 298 and 313K were 0.0097 and 0.0141mol/g of dry RB, respectively, after 72h. The desorbed amounts are 0.0085 and 0.01mol H2O/g of RB at 298 and 313K, respectively after 72h. A kinetic models of second order of the adsorption and desorption of water vapour fitted well the experimental data. Application of Van’t Hoff’s law at two temperatures (298 and 313K) yields the adsorption and desorption enthalpy. The adsorption enthalpy (stored energy) of RB increased with increasing contact time up to 5h. At this time the maximum enthalpy was about 30kJ/g dry bentonite, at which the clay has lost all the energy that could be released due to adsorption of water vapours. Then it shows a decrease in sorption energy when the time increases. On the other hand, the desorption enthalpy increases gradually with the increase of the time up to 72h then become constant, maximum enthalpy was 14.99kJ/g. The rate of water vapour adsorption was found to be very high so that the extracted energy from the bentonite surface would not be a problem in any practical utilization of this system.
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