Abstract
To improve the corrosion resistance of key components and ensure the service safety of marine equipment, here we combined femtosecond (fs) laser fabrication and magnetron sputtering deposition to develop micro/nanostructured amorphous TiNbZr films. Analysis of the compositional, microstructural, corrosion, and mechanical properties was conducted. The results showed that the TiNbZr films were amorphous, and spherical TiNbZr nanoparticles uniformly covered the fs laser-induced periodic fringe structure. A complex hierarchical micro/nanostructure was formed that was hydrophobic and showed enhanced adhesion strength. The TiNbZr films deposited on fs laser-treated substrates provided the best corrosion resistance, showing a self-corrosion current density of 116 nA/cm2, excellent passive ability, and pitting resistance. The microscratch test revealed that the micro/nanostructures doubled the binding strength of the TiNbZr/316L interface due to the compositional and structural gradients induced by an approximately 20 nm transition layer formed during fs laser processing. This work provides a new method for obtaining anti-corrosion films with a high adhesion strength for marine applications.
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