Abstract

An investigation of the process of micelle formation of amphiphilic molecules in dilute solution is described. This report shows that nuclear magnetic resonance using plutonium-31 is effective. Plutonium-31 measurements were made with a spectrometer under ambient conditions. The spectra were measured with proton decoupling, and the shifts are reported with respect to an internal capillary containing 85% H/sub 3/PO/sub 4/. The number of transients accumulated varied from 100 to 10,000. The critical micelle concentration in water is consistent with that previously determined. The spectra of the sample were compatible with the trialkylphosphine oxide structure reported previously. 17 references.

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