Abstract

Methanestibonic acid is obtained by hydrolysis of tetraalkoxymethylstiborane or by oxidation of dimethoxymethylstibine with H2O, in a mixture of methylenchloride and alcohol at 0 °C as a white amorphous powder. Reaction of the acid with 2,3-dimethyl-butane-2,3-diol yields MeSb[OC(Me),C(Me)2O]2, and with sodium hydroxide a sodium salt Na2[MeSb(OH)3O]2 · 6 H2O is obtained.

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