Metal-organic framework photonic crystals with bidisperse particles-based brilliant structural colors and high optical transparency for elaborate anti-counterfeiting

Abstract

Photonic crystals (PCs) have attracted great interest and wide applications in displays, printing, anti-counterfeiting, etc. However, two main challenges significantly hinder their applications: 1) the tradeoff between high optical transparency across the whole visible range and brilliant colors requiring a large refractive index contrast (Δn), and 2) the way of regulating structural colors by altering tens of different sizes. To address these issues, a new type of metal–organic framework (MOF)-based transparent photonic crystal (TPC) has been fabricated through self-assembling MOF particles into three-dimensional ordered structures which were then infiltrated by polydimethylsiloxane (PDMS). Compared to conventional PCs, these TPCs exhibit 1) both brilliant forward iridescent structural colors and high transmittance (>75 %) across the whole visible spectra range, and 2) conveniently adjustable colors based on bidisperse particles. The unique color-generating mechanism of the light diffraction by each plane lattice and the small Δn between MOF particles and PDMS are the keys to TPCs’ characteristics. Moreover, the prepared invisible anti-counterfeit labels can reversibly hide-reveal patterns with elaborate and exchangeable color contrast in a non-destructive way, showing potential applications in anti-counterfeiting, information encryption, and optical devices.