Metal substitution effect on superconductivity in barium intercalated ternary metal nitride chlorides

Abstract

We systematically studied barium cointercalated ternary metal nitride chloride superconductors of Ba(NH3)yZrHfxNCl (). X-ray diffraction and Raman spectra measurements show a systematical evolution of lattice constants and lattice dynamics upon Hf replacement for Zr. The superconducting transition temperature () increases monotonically from 11.7 K to 20.2 K with increasing the hafnium content in metal-nitrogen bilayers from 0 to 1. The upper critical field Hc2(0) for Ba(NH3)yHfNCl is estimated to be about 13.2 T. Accompanied by the remarkably increased , the highest energy phonon mode coupled most strongly with electronic system shows a moderate hardening with Hf substitution for Zr. This result suggests the reinforcement of pairing interaction with Hf substitution arises mainly from the evolution of electronic structure of metal d-band rather than from phonon modes.