Abstract

Two new coordination polymers are obtained: layered [Hdabco][Sc2(H20)2(OH)(tFBDC)3]-3/2C4HgO2 (1) (dabco=1,4-diazabicyclo[2.2.2]octane) and chain-like [Zn(CH3OH)4(oFBPDC)]-2CH3OH (2). They are formed by anions of perfluorinated terephthalic (tFBDC2) and biphenyl-4,4'-dicarboxylic (oFBPDC2) acids. The composition and structure of the obtained compounds are determined by the single crystal X-ray diffraction analysis.

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