Metal Halide Single Crystals RbCdCl3:Sn2+ and Rb3SnCl7 with Blue and White Emission Obtained via a Hydrothermal Process.

Abstract

Until now, effective blue light-emitting materials are essentially needed for the creation of white light and precise color renderings in real-world applications, but the efficiency of blue light-emitting materials has lagged far behind. Here, we present a hydrothermal method to synthesize tin-based metal halide single crystals (RbCdCl3:Sn2+ and Rb3SnCl7). Two single crystal materials with different shapes and phases can simultaneously be synthesized in the same stoichiometric ratio. Rb3SnCl7 has a bulk shape, while RbCdCl3:Sn2+ has a needle shape. The deep blue emission (436 nm) of RbCdCl3:Sn2+ can be obtained under the optimal excitation wavelength irradiation. However, pure blue emission (460 nm) to white light can be obtained by changing the excitation wavelength in Rb3SnCl7. The refinement spectra of the electronic structures of RbCdCl3:Sn2+ and Rb3SnCl7 are investigated by density functional theory. It is concluded that the difference in the distribution of Cl energy states leads to the existence of Cl local defect states, which is the reason for the rich luminescence of the two single crystals. These findings provide a path for realizing single-phase broadband white-emitting materials.