Abstract
Complexes of transition metals with chiral ligands are considered as catalysts. Among metal-containing organic complexes with semiconducting properties, compounds of the porphin series occupy a special place in electrocatalytic studies. The properties of the porphyrin macrocycle, their role in catalysis, and the influence of the nature of the metal on the catalytic properties of the complex are considered.
Highlights
Complexes of transition metals with chiral ligands are considered as catalysts
compounds of the porphin series occupy a special place in electrocatalytic studies
В этом случае, если толщина полупроводниковой пленки меньше глубины экранирования (для комплексов металлов она состаляет 10-6 – 10-5 см), возможны дополнительные эффекты, обусловленные инжекцией носителей тока из проводника (подложка) в полупроводник (катализатор)
Summary
Complexes of transition metals with chiral ligands are considered as catalysts. Among metal-containing organic complexes with semiconducting properties, compounds of the porphin series occupy a special place in electrocatalytic studies. Обладающих полу-проводниковыми свойствами, особое место в электрокаталитических исследо-ваниях занимают соединения ряда порфина. По механизму действия металлокомплексные катализаторы электросинтеза можно разделить на две группы: 1) металлокомплексы, координационная сфера которой остается неизменной и перенос электрона происходит по внешнесферному механизму без образования промежуточного комплекса между субстратом (А) и катализатором (редокс-пара P/Q): P+e↔Q
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