Abstract
Rapid reactions of hydrocarbon solutions of Mo/sub 2/(OR)/sub 6/(M triple bond M) compounds where R=t-Bu, i-Pr, and CH/sub 2/CMe/sub 3/ with the alkynes C/sub 2/H/sub 2/, MeC/sub 2/H, and MeC/sub 2/Me are reported. The ..mu..-acetylene and ..mu..-C/sub 4/H/sub 4/ adducts formed with the reaction products in the presence of pyridine have been isolated and characterized. X-ray diffraction and NMR studies of the adducts are reported. (BLM)
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