Abstract
NiO solid/hollow spheres with diameters about 100 nm have been successfully synthesized through thermal decomposition of nickel acetate in ethylene glycol at 200 °C. These spheres are composed of nanosheets about 3–5 nm thick. Introducing poly(vinyl pyrrolidone) (PVP) surfactant to reaction system can effectively control the products’ morphology. By adjusting the quantity of PVP, we accomplish surface areas-tunable NiO assembled spheres from ∼70 to ∼200 m 2 g −1. Electrochemical tests show that NiO hollow spheres deliver a large discharge capacity of 823 mA h g −1. Furthermore, these hollow spheres also display a slow capacity-fading rate. A series of contrastive experiments demonstrate that the surface area of NiO assembled spheres has a noticeable influence on their discharge capacity.
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