Mesoporous tin oxide for electrocatalytic CO2 reduction

Abstract

The increasing accumulation of CO2 in the atmosphere has been leading to serious environmental problems. Electrochemical reduction of CO2 is a potential means of carbon recycling for energy storage and environmental sustainability. However, it is limited by the lack of highly active and selective electrocatalysts. Here we demonstrate the development of mesoporous tin oxide (SnO2) for electrocatalytic CO2 reduction, which facilitates the adsorption and electrochemical reduction of CO2 inside mesopores. The highly-ordered and uniform pore sizes of the mesoporous SnO2 electrocatalyst favor the enhancement of formation of carbon monoxide (CO) and formate during the electrochemical reduction. The combined faradaic efficiencies of CO and formate reach a peak value of ∼80% at a current density of 5 mA cm−2 at −0.8 V vs. reversible hydrogen electrode. This work suggests attractive development of mesoporous electrocatalysts with a variety of pore size and structures for efficient energy conversion and electrochemical CO2 reduction.