Abstract
Polymers of intrinsic microporosity (PIMs) have attracted great attention for membrane separation applications due to their high free volume. Since the first report of PIM-1 in 2004, an array of new PIMs have been developed, including PIM-polyimides and Tröger's base PIMs. In gas separation, development of the PIM concept has led to two major advances across the previous Robeson upper bound for important gas pairs. PIMs have also been investigated for organic solvent nanofiltration, organophilic pervaporation, and a variety of other application areas.
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