Abstract
Chemically formed zirconium phosphate subjected to thermal treatment for various time intervals in the presence of phosphoric acid has been used for membrane formation. Membrane potential and membrane conductance measurements have been used to investigate the relationship between the ion-exchange capacity of zirconium phosphate and the electrochemical characteristics of the membranes using sodium chloride and magnesium chloride solutions of different concentrations. The results have also been used to estimate solute separation characteristics of the zirconium phosphate membranes using non equilibriumthermodynamics.
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