Mechanoresponsive Spin via Spin-Lattice Coupling in Organic Cocrystals.

Abstract

The response of crystal structure to external stimuli provides potential applications in the areas of detection, diagnosis, and repair. In this work, we fabricate two allotropic organic cocrystals, with different space groups and lattice parameters, with identical donor and acceptor molecules inside them. Under external stimuli, lattice vibration and electron-phonon coupling present pronounced differences in these two types of crystals, where different strengths of spin polarizations are observed. Furthermore, due to pronounced differences in coupling between lattice and spin inside the allotropic charge transfer crystals, the magnetic field presents a discrepant tunability on both transmission and fluorescence lifetimes. Through decreasing temperature or applying external electric field, the electron-phonon coupling coefficient presents a decreasing tendency, which will affect the dipole and dielectric constant in the allotropic crystals differently.