Mechanisms of swelling inhibition and seepage promotion of weathered crust elution-deposited rare earth ore by hydroxypropyl methyl cellulose

Abstract

In-situ leaching process of weathered crust elution-deposited rare earth ore (WCE-DREO) often faces problems such as poor permeability and occurrence of landslides. The main reasons are the swelling of clay minerals by water absorption and blockage of seepage channels by fine particles. This study proposed using hydroxypropyl methyl cellulose (HPMC) as a novel green swelling inhibitor with the combination of ammonium sulfate ((NH4)2SO4) as an efficient composite leaching agent. The swelling inhibition performance of HPMC on swelling inhibition was evaluated through linear swelling tests and mud ball immersion tests. The mechanisms of HPMC on swelling inhibition and seepage promotion were analyzed by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), Scanning electron microscopy (SEM), Surface area analysis (BET), X-ray photoelectron spectroscopy (XPS), Thermogravimetric analysis (TGA), and the contact angle, zeta potential and particle size distribution were characterized. The results indicated that HPMC showed a good performance on swelling inhibition, which improved with the increase of HPMC concentration. HPMC expels the water from the interlayer. Moreover, HPMC adsorbs onto the surface of clay minerals by hydrogen bonding to form a hydrophobic film, which can prevent the clay minerals from hydration swelling. Due to the electric neutrality property of HPMC, the electrostatic repulsion of clay minerals can be reduced. Therefore, the fine particles of the clay minerals can be bridged to form larger particles by the long carbon chain of HPMC which leads to expansion of the seepage channels as well as the improvement of the permeability of the ores. According to the column leaching tests, the novel leaching agent composed of 0.05 wt% HPMC and 2 wt% (NH4)2SO4 not only showed a good leaching capacity of rare earth, but also inhibited the swelling of clay and enhanced the seepage when comparing with traditional leaching agent ((NH4)2SO4). Developing a novel leaching agent benefits the green, safe and high-efficiency exploitation of WCE-DREO.