Abstract
Mechanisms of the electrode processes occurring on the iron metals which are complicated by the generation of a chemisorbed film on the surface are discussed. The film can be either partially reduced or desorbed at elevated temperatures. It can also be removed during the generation of fresh surface. In its absence, the overall reversible electrode reaction includes consecutive elementary steps of the charge transfer from active centers of adsorption and the step where unstable intermediate univalent metal ions undergo disproportionation.
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