Abstract

During the continuous casting (CC) of Ti-bearing steel, a steel lump can solidify in the mold (i.e., floater steel) more easily than in the Ti-free steels. This causes severe surface defects or even a breakout. We have examined the mechanisms of floater formation during the CC of 321 stainless steel by analyzing the inclusions in the floater steel and in the 321 steel that was sampled from the mold. Additionally, we calculated the disregistry between the metallic phases and common inclusions. The mineralogy and morphology of the inclusions were examined while using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). Thermodynamic calculations on the TixOy inclusions at different oxygen potentials were performed while using FactSage 7.2. Using this approach, we determined that ferrite nucleates grow on TiN and MgO inclusions following solidification, which then form micro-aggregates as a result of dynamic collisions and alliances. Analysis of the mold slag from the metallurgy stage indicated that altering the basicity and properties of the mold flux systematically might minimize the reaction between the slag and steel, which would achieve a coordinated control over lubrication and heat transfer.

Highlights

  • Austenitic, Ti-stabilized 321 stainless steel exhibits a remarkable resistance to intergranular corrosion over an extended temperature range

  • The formation of floaters is typically observed at the steel-slag interface within the mold after casting for 15 min., and approximately one fifth of the floater was exposed to the air

  • scanning electron microscopy (SEM), which showed that it had a porous structure between the floater steel and the covered slag

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Summary

Introduction

Austenitic, Ti-stabilized 321 stainless steel exhibits a remarkable resistance to intergranular corrosion over an extended temperature range. It is commonly used in applications, such as exhaust manifolds and expansion joints. The addition of titanium can cause a number of problems during the continuous casting (CC) of high Ti-bearing alloy steels. The severity of nozzle clogging and mold floaters in the case of Ti-bearing steels is significantly higher than that in the Ti-free steels. This is primarily because of heterogeneous nucleation of TiN on either Al2 O3 or

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