Mechanism of biochar-Cu-based catalysts construction and its electrochemical CO2 reduction performance

Abstract

Electrochemical CO2 reduction can convert CO2 into high-value-added products for special forms of energy storage and efficient carbon utilization for renewable electricity. To investigate the influence of biochar-Cu-based catalysts properties on electrochemical CO2 reduction performance, Cu is loaded onto rice husk-based biochar by impregnation method combined with pyrolysis and calcination in this study. The three synthesized biochar-Cu-based catalysts are tested for activity and electrochemical CO2 reduction performance in Flow Cell. The results show that biochar's properties, such as its high specific surface area, rich pore structure, and adjustable pore structure, provide sufficient sites for CO2 reduction. Urea can relatively increase the copper loading by 44 %, but it will also increase the clustering of copper. In the reduction performance test, the current density of char-Cu-700 is 2.08 times higher than that of char-Cu and 1.45 times higher than char-Cu-N at a reduction potential of -0.45 (V vs. RHE). The current density enhancement of the catalyst loaded on biochar with Cu particle size of 10 nm is about 50 % higher than that of the catalyst with a particle size of 20 nm. It indicates that the smaller the particle size of Cu at the nanoscale, the lower the average coordination of surface atoms and the greater the catalyst's reactivity. This study provides novel ideas for synthesizing biochar-Cu-based catalysts, lays part of the theoretical foundation for using biochar-Cu-based catalysts for electrochemical CO2 reduction, and provides experimental support for optimizing the catalyst structure.