Abstract

Using particle dynamics simulations, we investigate the strength and microstructure of agglomerates of wet frictional particles subjected to axial compression. The numerical model accounts for the cohesive and viscous effects of the binding liquid up to a debonding distance with the liquid assumed to be distributed homogeneously inside the agglomerate. We show that wet agglomerates undergo plastic deformation due to the rearrangements of primary particles during compression. The compressive strength is thus characterized by the plastic threshold before the onset of failure by the irreversible loss of wet contacts between primary particles. We find that the agglomerate plastic threshold is proportional to the characteristic cohesive stress defined from the liquid-vapor surface tension and the mean diameter of primary particles, with a prefactor that is a nearly linear function of the debonding distance and increases with size span. We analyze the agglomerate microstructure and, considering only the cohesive capillary forces at all bonds between primary particles, we propose an expression of the plastic strength as a function of the texture parameters such as the wet coordination number and packing fraction. This expression is shown to be consistent with our simulations up to a multiplicative factor reflecting the distribution of the capillary bridges.

Highlights

  • The agglomeration or granulation of solid particles is used in many sectors including powder metallurgy, chemical engineering, pharmaceutical industry, and iron-making processes to produce agglomerates or granules from small particles

  • The physical processes governing the growth of granules are complex due to the dynamic nature of granulation involving the collisions of particles and transport of the binding liquid inside a partially wet granular material [9,23,24,25,26,27]

  • By simulating the diametrical compression of spherical agglomerates, we find that, due to particle rearrangements, they show a plastic behavior with a threshold that we analyze as a function of friction coefficient and size span of primary particles

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Summary

Introduction

The agglomeration or granulation of solid particles is used in many sectors including powder metallurgy, chemical engineering, pharmaceutical industry, and iron-making processes to produce agglomerates or granules from small particles. The diametrical compression test is a simple way of measuring the tensile strength of powder compacts as the compressive strength (the stress at incipient failure of a granule) is proportional to the tensile strength of the granule [38] This method has, been mostly used to study the fracture stress of brittle materials composed of particles glued via solid bonds [39,40,41]. Wet granules have been much less investigated While their cohesive strength is mainly controlled by the Laplace pressure and surface energy of the liquid phase, the effects of granular texture resulting from the granulation process and material parameters are still poorly understood.

Numerical method and procedures
Numerical method
Ideal granules
Granule strength
Analytical model
Conclusions
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